Установка Docker Compose под Centos
Сначала ставим python-pip:

sudo yum install epel-release
sudo yum install -y python-pip
sudo pip install --upgrade pip

Далее ставим Docker Compose, при необходимости обновляем python:

sudo pip install docker-compose
sudo yum upgrade python*

Проверяем:

vi docker-compose.yml
 
my-test:
  image: hello-world
 
docker-compose up -d
docker-compose ps
 
Output of `docker-compose ps`
        Name           Command   State    Ports 
-----------------------------------------------
helloworld_my-test_1   /hello    Exit 0 
 
docker-compose stop